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In view of the expected long - term energy shortages, considerable effort is being expended to develop processes for upgrading low - quality energy sources

In view of the expected long-term energy shortages, considerable effort is being expended to
develop processes for upgrading low-quality energy sources to high-quality fuels. The flowsheet
shown in the next page Figure is an example of such a scheme. In it, high-sulfur coal, a fuel which
otherwise could not be used because of air quality standards, is gasified to produce a clean
synthetic natural gas (SNG). Powdered coal and steam per 1lb coal) are charged to a
reactor which at high temperature and pressure produces a complex mixture of gases including
10%(mole basis) methane. The heat for the reaction is provided by burning some of the charged
coal with oxygen introduced directly into the reactor. The raw product gas is cooled, treated for
removal of entrained ash, and sent to a second reactor, the shift converter. In this unit, the H2-to-CO
mole ratio of 0.56:1 is increased by converting 62.5% of the CO. The shifted gas, still containing
10%CH4, is next treated for removal of the acid gases, H2S and CO2. Finally, the residual gas,
containing 49.2%H2 on an H2O-free basis, is sent to a catalytic reactor which produces additional
methane. The final H2O-free product gas contains 5%H2,0.1%CO, and the rest CH4(mole basis).
Calculate all flows in the process based on a feed of 10000lbh coal and assuming 25% of the
carbon fed ultimately appears in the product.
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