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Instead of the conventional free radical polymerization of PS , you decide to control the polymerization by use of a RAFT agent, DDMAT: a .
Instead of the conventional free radical polymerization of PS you decide to control the polymerization by use of a RAFT agent, DDMAT:
a Draw the reaction for the fragmentation of the RAFT agent.
b Draw two possible polymeric radicals with different chain ends fragmented from the RAFT agent.
c Describe how the RAFT agent enables the uniform growth of polystyrene chains without obvious termination. Write down a chemical equilibrium reaction including polystyrene chains and DDMAT, followed by proper explanation.
d For RAFT polymerizations, what could increase the possibility of undesirable side reactions and terminations?
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