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Instead of the conventional free radical polymerization of PS , you decide to control the polymerization by use of a RAFT agent, DDMAT: a .
Instead of the conventional free radical polymerization of PS you decide to control the polymerization by use of a RAFT agent, DDMAT: a Draw the reaction for the fragmentation of the RAFT agent. b Draw two possible polymeric radicals with different chain ends fragmented from the RAFT agent. c Describe how the RAFT agent enables the uniform growth of polystyrene chains without obvious termination. Write down a chemical equilibrium reaction including polystyrene chains and DDMAT, followed by proper explanation. d For RAFT polymerizations, what could increase the possibility of undesirable side reactions and terminations?
Instead of the conventional free radical polymerization of PS you decide to control the polymerization by use of a RAFT agent, DDMAT:
a Draw the reaction for the fragmentation of the RAFT agent.
b Draw two possible polymeric radicals with different chain ends fragmented from the RAFT agent.
c Describe how the RAFT agent enables the uniform growth of polystyrene chains without obvious termination. Write down a chemical equilibrium reaction including polystyrene chains and DDMAT, followed by proper explanation.
d For RAFT polymerizations, what could increase the possibility of undesirable side reactions and terminations?
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