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Insulators are not good conductors for both electricity and heat: can you explain what is the relationship between their electric conductivity and heat transport (if

Insulators are not good conductors for both electricity and heat: can you explain what is the relationship between their electric conductivity and heat transport (if any)? In other words, I am asking if the same underlying process (or processes) accounts for the electronic vs. thermal properties of insulators (and/or other families of materials, such as metals).

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