Question
Lead(II) bromide, PbBr 2 , is a slightly soluble saltwith a K SP value of6.6 x 10 -6 . The equation for itsdissociation in water
Lead(II) bromide, PbBr2, is a slightly soluble saltwith a KSP value of6.6 x 10-6. The equation for itsdissociation in water is
PbBr2(s) <----------> Pb2+(aq) + 2Br-(aq)
What is the molar solubility of PbCl2 in distilledwater? I KNOW THE ANSWER IS 1.2 x 10 ^-2 mol/L
but I don\'t understand this part:
In the previous problem, you calculated the molar solubility ofPbBr2 in distilled water. Now consider themolar solubility of PbBr2 in a 3.55 M NaBrsolution. Sodium bromide is a freely soluble salt, andcompletely dissociates into its ions when dissolved in water:
NaBr(s) ==========> Na+(aq) + Br-(aq)
Therefore, a 3.55 M NaBr solution is 3.55 M inNa+ and 3.55 M in Br-. Whenthe PbBr2 is dissolved in this solution, itestablishes its usual equilibrium:
PbBr2(s) <----------> Pb2+(aq) + 2Br-(aq) KSP = 6.6 x 10-6
But in the 3.55 M NaBr solution, theBr- concentration will be 3.55 M,even before thePbBr2 dissociates. TheBr- formed in the dissociation ofPbBr2 will be in addition tothat already present.
What is the molar solubility of PbBr2 in the3.55 M NaBr solution?
Step by Step Solution
There are 3 Steps involved in it
Step: 1
we need to consider the common ion effect When PbBr2 is dissolved in a solution containing a h...Get Instant Access to Expert-Tailored Solutions
See step-by-step solutions with expert insights and AI powered tools for academic success
Step: 2
Step: 3
Ace Your Homework with AI
Get the answers you need in no time with our AI-driven, step-by-step assistance
Get Started