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Let's assume that a mixture of benzene ( 1 ) and toluene ( 2 ) at T = 1 0 5 C and P =

Let's assume that a mixture of benzene (1) and toluene (2) at T=105C and P=120
kPa obeys Raoult's law:
y1P=x1P1 sat
y2P=x2P2 sat
a) Adding eqns. 1 and 2, calculate x1 for this mixture at the given T and P. Once you
solve for x1, evaluate x2.
b) Next, calculate y1 and y2.
c) What is the value of the fugacity of component 1 in the vapor mixture ((hat(f1v)))?
d) What is the value of the fugacity of component 1 in the liquid mixture (hat(f)1l)?
e) The following is a "flash" equipment that operates at constant T and P. At T and P, a
mixture of liquid and vapor separates into a pure vapor mixture (V) and a pure liquid
mixture (L). One mole of a mixture F of liquid and vapor enters the flash tank at a mole
fraction z1=0.33.V and L are the number of moles of the vapor and liquid mixtures
leaving the flash.
Write a total mole balance for the flash tank.
Write a mole balance for component 1.
Using these two mole balance equations, solve for V and L as functions of z1,x1,
and y1
Using your values of y1,y2,x1,x2, calculated in (a) and (b), what are V and L?
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