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O 3 ( 3 5 % ) . As a consultant you have been asked to report on the feasibility of two processes to produce

O3(35%). As a consultant you have been asked to report on the feasibility of two processes to
produce aluminum:
Thermal decomposition:
Al2O32Al+1.5O2
Al2O3+3CO=2Al+3CO2
CO reduction:
For thermal decomposition the proposed temperature is 2000oC. For CO reduction the proposed
operating temperature is 1500oC and proceeds at pCO+pCO2=1atm.
Assess the thermodynamic feasibility for each option considering such factors as achieving ultra-
low oxygen partial pressure and the equilibrium for the CO-CO2 system.
Hint: try to calculate the concentration/partial pressure of components from equilibrium
relationships and then assess the feasibility of calculated values. For CO reduction, you must also
consider C+CO2=2CO reaction. Also, note that a reaction might be possible from
thermodynamics perspective, but impractical.
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