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P 1 0 - 7 B B The dehydration of n - butyl alcohol ( butanol ) over an alumina - silica catalyst was investigated
P The dehydration of butyl alcohol butanol over an aluminasilica catalyst was investigated by
J F Maurer PhD thesis, University of Michigan The data in Figure P were obtained at
in a modified differential reactor. The feed consisted of pure butanol.
a Suggest a mechanism and ratelimiting step that are consistent with the experimental data.
b Evaluate the ratelaw parameters.
c At the point where the initial rate is a maximum, what is the fraction of vacant sites? What is the
fraction of occupied sites by both A and vacant
d What generalizations can you make from studying this problem?
e Write a question that requires critical thinking and then explain why your question requires critical
thinking. Hint: See Preface Section I.
f Apply one or more of the six ideas in Preface Table P page xxviii, to this problem.
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