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P 1 0 - 7 B B The dehydration of n - butyl alcohol ( butanol ) over an alumina - silica catalyst was investigated

P10-7BB The dehydration of n-butyl alcohol (butanol) over an alumina-silica catalyst was investigated by
J. F. Maurer (Ph.D. thesis, University of Michigan). The data in Figure P10-7B were obtained at 750F
in a modified differential reactor. The feed consisted of pure butanol.
(a) Suggest a mechanism and rate-limiting step that are consistent with the experimental data.
(b) Evaluate the rate-law parameters.
(c) At the point where the initial rate is a maximum, what is the fraction of vacant sites? What is the
fraction of occupied sites by both A and B?% vacant =0.41
(d) What generalizations can you make from studying this problem?
(e) Write a question that requires critical thinking and then explain why your question requires critical
thinking. Hint: See Preface Section I.
(f) Apply one or more of the six ideas in Preface Table P-4, page xxviii, to this problem.
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