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= P8.42 In Problem P8.39, you obtained the result Imax = 1/2[V 41 kT/ti? 1] Using this result, estimate T for the simulated 'H35Cl rota-

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= P8.42 In Problem P8.39, you obtained the result Imax = 1/2[V 41 kT/ti? 1] Using this result, estimate T for the simulated 'H35Cl rota- tional spectra shown in parts a and b of the following figure. Give realistic estimates of the precision with which you can determine T from the spectra. In generating the simulation, we assumed that the intensity of the individual peaks is de- termined solely by the population in the originating state and that it does not depend on the initial and final J values. Intensity well illin 2800 3100 3200 2900 3000 Frequency (cm-1. (a) Intensity w 2800 3100 3200 2900 3000 Frequency (cm-1) (b) b = P8.42 In Problem P8.39, you obtained the result Imax = 1/2[V 41 kT/ti? 1] Using this result, estimate T for the simulated 'H35Cl rota- tional spectra shown in parts a and b of the following figure. Give realistic estimates of the precision with which you can determine T from the spectra. In generating the simulation, we assumed that the intensity of the individual peaks is de- termined solely by the population in the originating state and that it does not depend on the initial and final J values. Intensity well illin 2800 3100 3200 2900 3000 Frequency (cm-1. (a) Intensity w 2800 3100 3200 2900 3000 Frequency (cm-1) (b) b

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