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Polymer Chemistry please This problem involves plotting a phase diagram for mixtures of poly ( isobutylene ) ( PIB ) and 1 , 4 -

Polymer Chemistry please
This problem involves plotting a phase diagram for mixtures of
poly(isobutylene)(PIB) and 1,4-poly(butadiene)(PB) in the melt state. For simplicity
assume equal molecular weights and monodisperse polymers, M?PIB=MPBPB, and a
common density of =0.87gcm3.
Determine the molecular weight required to place the critical temperature at 100C.
Calculate the spinodal (stability) curve and plot this on a Figure with CdelGmdeliGm(:h2:)2M(A2molg)25
C.
Calculate the binodal (equilibrium) curve and include this in the phase diagram.
Hint: This problem is easily completed using a numerical solution for delGmdeli based on
the symmetric form ofGm.
TABLE 6.1
Representative Values of the Monomer Volume, Characteristic Ratio, Statistical Segment Length, Persistence Length, Packing Length,
Segment Length for a100 Reference Volume, Kuhn Length, and Molar Mass per Kuhn Length, for Various Flexible Polymers, Calculated
from the Experimental Quantities, (:h2:)2M(A2molg)
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