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Prepare an alum pe-pH diagram at 279K and room temperature (293K). Use the chemical equilibrium expressions below for room temperature (293K) conditions. Use the expressions
Prepare an alum pe-pH diagram at 279K and room temperature (293K). Use the chemical equilibrium expressions below for room temperature (293K) conditions. Use the expressions to create two graphs and show equilibrium lines for Al+3/Al(OH)3(am),AlOH2+/Al(OH)3(am), and Al(OH)4/Al(OH)3 (am). Al(OH)3(am)=Al2++3OHAl(OH)3(am)+H2O=Al(OH)4+H+All3++H2O=AlOH2++H+H2O=H++OHK=10315K=101235K=105.5K=1014 To convert these expressions to 279K, employ the Yan't Hoff Expression. Below are thermodynamic data Also recall that the yant- hoff equation is: lnK2K1=RH(t21t11) Where H is the enthalpy of formation Hint: The key to solving this problem is to write expressions that relate aluminum species (i.e. Al3+,AlOH2+, and Al(OH)4 to H+ and Al(OH)3(am). Use the K values for the two temperatures to do this. The equilibrium K values above are for 293K; you can also convert these to 279K using the yant hoff equation
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