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Problem 2 . Development of a Catalytic Reaction Rate Expression Consider the catalytic reaction A P . A possible reaction mechanism is given below where
Problem Development of a Catalytic Reaction Rate Expression
Consider the catalytic reaction A possible reaction mechanism is given below where
denotes an active catalytic site.
Chemisorption of :
Surface reaction: As Rs
Desorption of :
Derive expressions for the reaction rate for the following two cases:
a Step Chemisorption of specie A is rate controlling
b Step Surface reaction is rate controlling
Derive the linearized from of the rate equations for the above two cases that would be
used to obtain initial estimates of the rate and adsorption equilibrium parameters from
experimental data on the initial rates, partial pressures of specie A and R and the
overall thermodynamic equilibrium constant.
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