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Problem 2 : LLE in mixtures of Polystyrene ( PS ) and Methyl Cyclohexane ( MCH ) Experimental measurements of LLE ( T vs .

Problem 2: LLE in mixtures of Polystyrene (PS) and Methyl Cyclohexane (MCH)
Experimental measurements of LLE (T vs. volume fractions) for MCH(1) and PS(2) at
atmospheric pressure are reported below.
The molecular weight of PS and MCH are 16500gmol(average) and 98.2gmol, while the
density (gL) of the polymer and solvent is given as a function of T(K) by
PS=1175-0.3976T
MCH=1022-0.863T
2a) Estimate the critical volume fraction of PS using the simple version of the FH model (see
problem 1) and compare the value with the experimental data above.
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