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Production of Monoethanolamine ( MEA ) A new facility to produce Monoethanolamine ( MEA ) is being considered due to an increase in demand. Therefore,

Production of Monoethanolamine (MEA)
A new facility to produce Monoethanolamine (MEA) is being considered due to an
increase in demand. Therefore, you have been requested to design a plant to produce
10,000 metric tons per annum of MEA (at 99.5% purity). The plant is to be located in
Richards Bay, South Africa.
The following feed streams are available:
Ammonia feed is available at 10 atm and 50\deg C from an adjacent plant.
Ammonia is available as an aqueous solution of 55 wt.% of ammonia and 45
wt.% water.
Ethylene Oxide (99.99% pure) is available at 5 atm and 40\deg C.
A reaction temperature of 150 oC is maintained in the reactor, and a pressure
of 160 atmospheres to avoid the evaporation of ammonia.
Under specified conditions of reaction, only MEA is produced when the feed
ratio of Ammonia /Ethylene oxide is 10.
The plant should operate for 330 days a year to allow for shutdown and
maintenance.
The chemical equation is
NH3+ C2H40= C2H7NO
The heat of formation at standard condition is : H\deg rxn =-104.3 kj/mol
The entropy at standard conditions is :
G\deg rxn=-75.15 kj/mol
1. Calculate the reaction equilibrium
2. Calculate the composition equilibrium (find x)

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