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Q 1 : a ) Define passivity. b ) A copper sheet of dimensions 9 c m 4 c m 1 c m , is

Q1: a) Define passivity.
b) A copper sheet of dimensions 9cm4cm1cm, is exposed to an acid solution, after 24 hours, the loss of copper due to corrosion is 1510-3 grams. Calculate:
the current density (i) in Acm2,
the corrosion rate CR in mmy.
=a*nF+i
CR=
knowing that atomic weight =63.54gmol,=8.96gcm3.
Q2: For the corrosion cell: Fe|Fe+2(10-3)||Cu+2(10-4)|Cu
Draw the cell and write equations to describe the reactions which occur at each electrode?
Calculate the maximum possible potential of the resulting corrosion cell? Eell =?
Which electrode is the anode in this corrosion cell & why?
Draw the polarization diagram of this cell and label on it all the important information. Consider the io,H2=10-8 for copper & io,H2=10-6 for iron.
i. Draw the diagram indicating all the important points on it?
ii. What applied current is necessary to cause passivation?
iii. What applied current is necessary to maintain passivity?
Epp of 0.1V(SCE), and a critical anodic current density icrit. of 1mAcm2, passive current of 1Acm2 and the breakdown potential 0.5V :
Q3:
a) An active - passive metal in particular corrosion media has a primary passive potential Epp of 0.1V(SCE), and a critical anodic current density icrit. of 1mAcm2, pass current of 1Acm2 and the breakdown potential 0.5V : i. Draw the diagram indicating all the important points on it?
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