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Q 1 . A first - order, heterogeneous and irreversible reaction, A ( g ) B ( g ) , is taking placed within a

Q1. A first-order, heterogeneous and irreversible reaction, A (g)B(g), is taking placed
within a packed bed reactor with a spherical, porous catalyst pellets of 3cm diameter. The
reactor is designed to achieve 98% conversion with the residence time of 16 minutes. The
catalyst bed has a voidage of 0.4.
a) Calculate the effective diffusivity (De) for the reactant within the catalyst particle
(cm2s) when the Thiele modulus of this system is 2.5. Assume the reactor operates
isothermally and that external mass-transfer resistance is negligible.
b) To what diameter should the pellet be reduced if the internal effectiveness factor is to
be 0.85? A step in this problem requires numerical solving. This can be done using any
method or software and does not need to be attached.
c) What conversion do you predict if the pellets were increased 40% in diameter to reduce
pressure drop in the reactor?
d) For diffusional limitation to be considered insignificant, the internal effectiveness must
be higher than 0.95. A new catalyst particle is designed with Sg is decreased 30%,p is
reduced by 20%, and effective diffusivity (De) increases 100% compared to those in part
a). Determine the maximum diameter of the new catalyst particle to have an internal
effectiveness of 0.95? A step in this problem requires numerical solving. This can be
done using any method or software and does not need to be attached.
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