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Q 5 ) Relative volatility and activity coefficients of an azeotrope A sharp separation of benzene ( B ) and cyclohexane ( C H )
Q Relative volatility and activity coefficients of an azeotrope
A sharp separation of benzene and cyclohexane by distillation is impossible because of
an azeotrope at as shown by the data of KC Chao PhD thesis, University of Wisconsin
At atm:
a Use the data to calculate and plot the relative volatility of benzene with respect to
cyclohexane versus benzene composition in the liquid phase. What happens in the vicinity of the
azeotrope?
b Estimate the composition of the azeotrope. Is it a maximum boiling or minimumboiling
azeotrope?
c Using a process simulator with the Wilson equation to compute and plot the activity
coefficients. How well do they compare with the experimental data?
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