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Q1) The vapour pressure, p, of nitric acid varies with temperature as follows: 0/C 0 20 40 50 70 80 90 100 p/kPa 1.92

 

Q1) The vapour pressure, p, of nitric acid varies with temperature as follows: 0/C 0 20 40 50 70 80 90 100 p/kPa 1.92 6.38 17.7 27.7 62.3 89.3 124.9 170.9 What are: (a) the normal boiling point (b) the enthalpy of vaporization of nitric acid? Q2) Calculate the melting point of ice under a pressure of 50 bar. Assume that the density of ice under these conditions is approximately 0.92 g cm' and that of liquid water is 1.00 g cm. Q3) An open vessel containing (a) water, (b) benzene, (c) mercury stands in a laboratory measuring 5.0 m 5.0 mx 3.0 m at 25C. What mass of each substance will be found in the air if there is no ventilation? (The vapour pressures are (a) 3.2 kPa, (b) 13.1 kPa, (c) 0.23 Pa.)

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1a We have HNO3 and we have to determine its boiling point and enthalpy of vaporization We know that d ln p dt vap H RT2 d ln p vap H RT2 dT d ln p va... blur-text-image

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