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Q=N!qN;q=qEqVqTqRqR,diamtomic=RT;qR,polyatomic=21(ABCT3)21;qV=modes1exp(TVib)1qT=(h22m)23V;qE=jexp(Ej)Gf=kNTlnNq=nRTlnNq; 1. Use the following information to find the Gibbs Free Energy of formation for 1.00 bar NO2 at 298.15K (i.e. find Gf.NO2(298.15K) ): a)
Q=N!qN;q=qEqVqTqRqR,diamtomic=RT;qR,polyatomic=21(ABCT3)21;qV=modes1exp(TVib)1qT=(h22m)23V;qE=jexp(Ej)Gf=kNTlnNq=nRTlnNq; 1. Use the following information to find the Gibbs Free Energy of formation for 1.00 bar NO2 at 298.15K (i.e. find Gf.NO2(298.15K) ): a) Write a balanced chemical equation for the formation reaction for NO2. b) Write an equation for Gf,NO2(T) in terms of the partition functions. c) Find qtrans./V for each molecule, perform dimensional analysis and give the units. d) Find qrot. for each molecule, use dimensional analysis to demonstrate it is unitless. e) Find qvib.qelec. for each molecule, use dimensional analysis to demonstrate it is unitless. f) Use your answers for b) through e) to find Gf,NO2(T=298.15K) and comment on the feasibility of the reaction. Q=N!qN;q=qEqVqTqRqR,diamtomic=RT;qR,polyatomic=21(ABCT3)21;qV=modes1exp(TVib)1qT=(h22m)23V;qE=jexp(Ej)Gf=kNTlnNq=nRTlnNq; 1. Use the following information to find the Gibbs Free Energy of formation for 1.00 bar NO2 at 298.15K (i.e. find Gf.NO2(298.15K) ): a) Write a balanced chemical equation for the formation reaction for NO2. b) Write an equation for Gf,NO2(T) in terms of the partition functions. c) Find qtrans./V for each molecule, perform dimensional analysis and give the units. d) Find qrot. for each molecule, use dimensional analysis to demonstrate it is unitless. e) Find qvib.qelec. for each molecule, use dimensional analysis to demonstrate it is unitless. f) Use your answers for b) through e) to find Gf,NO2(T=298.15K) and comment on the feasibility of the reaction
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