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Safety Analysis: COMBUSTION OF METHANE Scenario: Your company/research group is designing a process that involves capturing 1.08mol methane and 1.62mol oxygen in a rigid 35.4L
Safety Analysis: COMBUSTION OF METHANE Scenario: Your company/research group is designing a process that involves capturing 1.08mol methane and 1.62mol oxygen in a rigid 35.4L container at 539.5K. The container is considered safe for use up to 6.0 bar and 900K (if either is exceeded, the container is not safe). Your job: A) Perform a safety analysis to determine if the container can withstand accidental combustion of the contents by the reaction: CH4+3/2O22H2O+CO2+heat Now consider that all of the heat of combustion has equilibrated within the system of water and carbon dioxide. a. Use the new temperature to find the total molecular partition function for water and carbon dioxide. b. Use the new temperature and partition functions (and numerical or analytical derivates) to find the entropy the water and carbon dioxide in the system (separately). c. What was the total change in entropy for the system after complete combustion and equilibration? d. What was the total change in energy for the system after complete combustion and equilibration? Can the container withstand combustion of the contents
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