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Serbest radikal polimerizasyonlarda sonlandrma kt iin hz sabitleri 1x108 L/mol s mertebesinde olabilir. 60 C'de ditert-btil peroksit tarafndan balatlan stirenin polimerizasyonunu ele alalm. Benzen iinde

Serbest radikal polimerizasyonlarda sonlandrma kt iin hz sabitleri 1x108 L/mol s mertebesinde olabilir. 60 C'de ditert-btil peroksit tarafndan balatlan stirenin polimerizasyonunu ele alalm. Benzen iinde 0,01 M peroksit ve 1,0 M stiren zeltisi iin, balang polimerizasyon hz 1,5x10-7 mol/Ls ve retilen polimer 138.000'dir. (a) Yukardaki bilgilerden, 60C'de stiren iin kp tahmini yapn. (b) Bu sistemdeki polimerizasyonun ilk aamalarnda bir makroradikalin ortalama mr nedir?

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