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Soru 1 ( 5 0 / 1 0 0 ) : n - oktanol ( 1 ) ve n - dekan ( 2 ) s

Soru 1(50/100): n-oktanol(1) ve n-dekan(2) sv karmlarnn atmosfer basncndaki 300K
scaklktaki karmadan kaynakl ortaya kan s deiimleri verisi llm ve aadaki eitlik
elde edilmitir:
H=x1x2(A+B(x1-x2)),Jmol
Burada A=2476;B=-1456.2
a) Bu ikili karm iin ?bar(H)1 ve ?bar(H)2 ksmi zelliklerini x1 mol fraksiyonuna karn 0-1 aralnda
0.1 adm artm esasl(0,0.1,0.2,dots,0.9,1.0 hesaplayp uygun bir bilgisayar program
kullanarak (Python-Matplotlib modl veya MATLAB)x1' e gre grafiini iziniz (ayn
grafikte iki ksmi zellik de yer almaldr).
b) Bu ikili karma ait ?bar(H)1 ve ?bar(H)2 ksmi zelliklerini x1 niceliinin bir fonksiyonu haline
getirecek eitlikleri (ikisinin de y=ax13+bx12+cx1+d biiminde 3. derece polinom bir
fonksiyona uymakta olduklar esasl) belirleyiniz. Eitliklerdeki a,b,c ve d katsaylarn,
aadaki aralar zerinden hesaplatnz.
Excel kullanarak
Bir bilgisayar program kullanarak (Python-Numpy modlndeki polyfit) veya
MATLAB)
VER: H1=1019.8Jmol,;,H2=3992.2Jmol
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