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Speculate on why the relaxation time for 13C on a 90 degree tip is so much longer than 20 degree. What about 29Si? How can

Speculate on why the relaxation time for 13C on a 90 degree tip is so much longer than 20 degree. What about 29Si? How can you speed this up? Finally, if 20 degree works, why not 5 degree, or 1 degree? I do not have any other information.


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