Answered step by step
Verified Expert Solution
Question
1 Approved Answer
tabul methacrylate was polymerized at a mass concentration of 200 g dm in toluene usine hisisobutyronitrile as initiator at a mass concentration of 1.64x
tabul methacrylate was polymerized at a mass concentration of 200 g dm in toluene usine hisisobutyronitrile as initiator at a mass concentration of 1.64x 10-2 g dm and a reaction nnerature of 60 C. Calculate the initial rate of polymerization and the molar mass of the polymethyl methacrylate) formed in the initial stages of the reaction given that the relevant rate coefficients at 60 C are: Initiator dissociation, k=8.5x 10-6 s-1 Propagation, k, =833 dm3 mol- s- Termination, k, =9.3 x 10 dm mol- s- Transfer to monomer, kM=3.93 x 10-3 dm mol-1s- Transfer to solvent, k,=7.34 x 10-3 dm mol- s- Assume that the initiator efficiency f=0.7, that termination by combination is negligible, and that the density of the initial solution of MMA in toluene is 860 g dm. %3D %3D uitiator dissociation.
Step by Step Solution
★★★★★
3.45 Rating (168 Votes )
There are 3 Steps involved in it
Step: 1
The expression for initial rate of polyme...Get Instant Access to Expert-Tailored Solutions
See step-by-step solutions with expert insights and AI powered tools for academic success
Step: 2
Step: 3
Ace Your Homework with AI
Get the answers you need in no time with our AI-driven, step-by-step assistance
Get Started