Question
The connection between the number of microstates, W , andthe entropy, S , of a system is expressed by theBoltzmann equation S = k ln
The connection between the number of microstates,W, andthe entropy, S, of a system is expressed by theBoltzmann equation
S=klnW
where k is the Boltzmann constant permolecule (particle), 1.38×10?23 J/(K?particle). From thisequation the entropy change, ?S, for a system can berelated to the change in the number of microstates as
?S=klnWfinalWinitial
where Wfinal in the final number ofmicrostates and Winitial is the initial numberof microstates.
A gaseous system undergoes a change in temperature and volume.What is the entropy change for a particle in this system if thefinal number of microstates is 0.424 times that of the initialnumber of microstates?
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answer From the equation S klnWfinalWinitial the entropy change for the particle is S kln0424 kln435 Therefore the entropy change for the particle is ...Get Instant Access to Expert-Tailored Solutions
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Physical Chemistry
Authors: Thomas Engel, Philip Reid
3rd edition
805338423, 080533842X, 978-0321812001
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