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The Deacon process for production of chlorine involves the gas - phase catalytic reaction:Furusaki ( 1 9 7 3 ) studied the kinetics of this

The Deacon process for production of chlorine involves the gas-phase catalytic reaction:Furusaki (1973) studied the kinetics of this reversible reaction, with a CuCl2, KCl, SnCl2-on silicacatalyst in differential and integral reactor. The rate of disappearance of HCl could be correlated by theequation:()221212141222211ClHClOHClOHClCKCKCCKCCkr++=(i) Devise a series of fundamental steps of adsorption and surface reaction which will give the aboverate expression.(ii) The rate data at 350oC, obtained in the differential reactor with a feed of HCl and air (no Cl2 orH2O), is as follows:Rate 106/mg mol/(gcatalyst. s)10.511.210.313.512.815.215.315.7610HClC /mg mol/cm30.240.270.330.440.450.680.740.89Using these data, evaluate as many of the constants, ,,1Kk and 2K , as possible.

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