Question
The diffusivity of chloroform in air was measured using an Arnold cell at 298 K and 1 atm. The liquid density of chloroform at 298
The diffusivity of chloroform in air was measured using an Arnold cell at 298 K and 1 atm. The liquid density of chloroform at 298 K is 1.485 g/cm3 and its vapor pressure at 298 K is 2.67x104Pa. Initially, the liquid chloroform surface was 7.4 cm from the top of the tube, and after 10 hours the liquid surface dropped to 6.96 cm. If the concentration of chloroform is zero at the top of the tube, what would be the gas diffusion coefficient of chloroform in air? Compare your result for binary-diffusion coefficient to the value predicted by Fuller, Schettler, Giddings correlation.
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