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The equilibrium interatomic spacings of the Na halides and their melting points are listed below. Explain the trend observed. NaF NaCl NaBr Nal Spacing,

  

The equilibrium interatomic spacings of the Na halides and their melting points are listed below. Explain the trend observed. NaF NaCl NaBr Nal Spacing, nm Melting point, C 0.23 0.28 0.29 0.32 988 801 740 660 (b) Explain the melting point trends observed for the alkali metal chlorides as one goes from HCI (-115.8C) to CsCl. (c) Which of these pairs of compounds would you expect to have the higher melting points; CaF2 versus ZrO2; UO, versus CeO2; CaF2 versus Cal2? Explain.

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