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The following are the binding energies for electrons in iron relative to the Fermi level (work function = 4 eV}. L shell: M shell: L1

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The following are the binding energies for electrons in iron relative to the Fermi level (work function = 4 eV}. L shell: M shell: L1 (ls orbital): 849 eV M1 (3s orbital): 91.5 eV L2 (2p 1,52 orbital]: T205 eV M33 (3p 152 8: 3.22 orbitals): 53 eV L3 2p 3;"? orbital]: 7'0? eV V (hybridized 3d orbitals. also the valence band): extend continuously from 5 eV to 0 eV We are exciting the iron atoms with photons of energy 1000 eV. Note: V orbital (valence band) belongs to the M shell; for this problem, you do n_ot need to use orbitals of the next element in the periodic table. 1) List all the possible LMM Auger peaks and their approximate energies, using the energy levels provided above. Ignore the possible \"selection rule\" for these quantum transitions {if you are familiar with such concepts). 2) In an XPS experiment, what would be the kinetic energy (of electrons right outside the sample surface) of the 2p 1,52 peak

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