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The following data were obtained from the gas phase reaction A + B 3C carried out in a constant volume bomb equipped with a pressure

The following data were obtained from the gas phase reaction

A + B 3C

carried out in a constant volume bomb equipped with a pressure gauge for monitoring the progress of the reaction.

Time, min

Total pressure, psig

0

59

110

64

170

67

260

69

390

72

610

75

1070

78

The bomb initially contains 30% A, 40% B and 30% inerts at 150C.

A. Find a first order irreversible rate expression for the data.

B. Comment on the suitability of the rate expression.

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