Question
In 2009, it was reported that a Mo-Mo quintuple bond (10, 2T, and 25 bonds) could be formed by reducing a quadruple-bonded dimolybdenum amidinate
In 2009, it was reported that a Mo-Mo quintuple bond (10, 2T, and 25 bonds) could be formed by reducing a quadruple-bonded dimolybdenum amidinate complex with KC8. Ar. Ar Ar- 4- Li[HC(N-2, 6- i-PrC6H3)2] 2 eq. KCg Mo Mo 4K* Mo Mo. Mo: Mo Ar Ar Ar Ar= Ar Ar The chemical reduction with KCg caused the Mo-Mo bond distance to decrease from ca. 2.08 to 2.02 A. Using only the 4d orbitals on Mo and the appropriate d-electron count, construct an MO diagram that accounts for the formation of the quintuple bond. Assume D2h symmetry. Show all work.
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