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The gas - phase reaction 1 2 N 2 + 3 2 H 2 l o n g r i g h t a r

The gas-phase reaction
12N2+32H2longrightarrowNH3
is to be carried out isothermally first in a flow reactor. The molar feed is 50%H2 and 50%N2, at a
pressure of 16.4atm and at a temperature of 227C.
(a) Construct a complete stoichiometric table.
(b) Express the concentrations in moldm3 of each for the reacting species as a function of conversion.
Evaluate CA0,, and , and then calculate the concentrations of ammonia and hydrogen when the
conversion of H2 is 60%.(Ans.: CH2=0.1moldm3)
(c) Suppose by chance the reaction is elementary with kN2=40dm3mols. Write the rate of reaction
solely as a function of conversion for (1) a flow reactor and for (2) a constant-volume batch
reactor.
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