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The Gibbs energy can be used to predict phase separation. We derived the Gibbs energy of a mixture as g = x _ ( i

The Gibbs energy can be used to predict phase separation. We derived the Gibbs energy of a mixture as g= x_(i)g_(i)+RT x_(i)lnx_(i)+g^(E). Use a reference state of the pure species at system T and P so the first term is zero. This is then equivalent to \Delta g_(mix )(\Delta g_(mix )=RT x_(i)lnx_(i)+g^(E)). For the following mixtures, assume the three-suffix Margules equation accurately models g^(E). a) Given a mixture of species a and b,\gamma _(a)^(\infty )=6 and \gamma _(b)^(\infty )=32. Plot \Delta (g_(mix ))/(R)T vs x_(a) and determine the number of phases, the composition of each phase, and overall \Delta (g_(mix))/(R)T for the solution at (i) x_(a)=0.1,(ii) x_(a)=0.5, and (iii) x_(a)=0.8. b) Is a miscible, partially miscible, or immiscible in b ? c) Given a mixture of species a and c,\gamma _(a)^(\infty )=0.8 and \gamma _(c)^(\infty )=0.2. Plot \Delta (g_(mix))/(R)T vs x_(a) and determine the number of phases, the composition of each phase, and overall \Delta (g_(mix))/(R)T for the solution at (i) x_(a)=0.1,(ii) x_(a)=0.5, and (iii) x_(a)=0.8. d) Is a miscible, partially miscible, or immiscible in c ?

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