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The Gibbs energy can be used to predict phase separation. We derived the Gibbs energy of a mixture as g = x _ ( i
The Gibbs energy can be used to predict phase separation. We derived the Gibbs energy of a mixture as g xigiRT xilnxigE Use a reference state of the pure species at system T and P so the first term is zero. This is then equivalent to Delta gmix Delta gmix RT xilnxigE For the following mixtures, assume the threesuffix Margules equation accurately models gE a Given a mixture of species a and bgamma ainfty and gamma binfty Plot Delta gmix RT vs xa and determine the number of phases, the composition of each phase, and overall Delta gmixRT for the solution at i xaii xa and iii xa b Is a miscible, partially miscible, or immiscible in b c Given a mixture of species a and cgamma ainfty and gamma cinfty Plot Delta gmixRT vs xa and determine the number of phases, the composition of each phase, and overall Delta gmixRT for the solution at i xaii xa and iii xa d Is a miscible, partially miscible, or immiscible in c
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