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The hydrogen exchange reaction is shown as below: H + H _ 2 H _ 2 + H The barrier height is 3 8 .

The hydrogen exchange reaction is shown as below:
H+H_2H_2+H
The barrier height is 38.2kJmol^-1 at 300K. The activated complex structure is a symmetric linear arrangement of the three atoms with the internuclear distance of 0.90\times 10^-10m. The vibrational wavenumbers for H_3 are 2184cm^-1(symmetric stretch) and 979cm^-1(doubly degenerate bend). The H_2 has only one vibrational mode and its vibrational wavenumber is 4395.2cm^-1. The H_2 equilibrium distance is 0.7416\times 10^-10m. The electronic partition functions, q_e, of H and H_3 are 2. Calculate the rate constant for the hydrogen exchange reaction using the simple transition-state theory. Given: q_t=(2\pi mkT/h^2)^3/2v ; q_t=8\pi ^2IkT/\sigma h^2 ; q_v=1/1-e^-hv/kT

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