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The hydrogen exchange reaction is shown as below: H + H _ 2 H _ 2 + H The barrier height is 3 8 .
The hydrogen exchange reaction is shown as below: HHHH The barrier height is kJmol at K The activated complex structure is a symmetric linear arrangement of the three atoms with the internuclear distance of times m The vibrational wavenumbers for H are cmsymmetric stretch and cmdoubly degenerate bend The H has only one vibrational mode and its vibrational wavenumber is cm The H equilibrium distance is times m The electronic partition functions, qe of H and H are Calculate the rate constant for the hydrogen exchange reaction using the simple transitionstate theory. Given: qtpi mkThv ; qtpi IkTsigma h ; qvehvkT
The hydrogen exchange reaction is shown as below:
HHHH
The barrier height is kJmol at K The activated complex structure is a symmetric linear arrangement of the three atoms with the internuclear distance of times m The vibrational wavenumbers for H are cmsymmetric stretch and cmdoubly degenerate bend The H has only one vibrational mode and its vibrational wavenumber is cm The H equilibrium distance is times m The electronic partition functions, qe of H and H are Calculate the rate constant for the hydrogen exchange reaction using the simple transitionstate theory. Given: qtpi mkThv ; qtpi IkTsigma h ; qvehvkT
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