Question
the mass spectrum of compound A showed the M+ at 106, and an M+2 at 108 in a 3:1 relative intensity ratio. When A was
the mass spectrum of compound A showed the M+ at 106, and an M+2 at 108 in a 3:1 relative intensity ratio.
When A was heated with KOC(CH3)3 in t-butanol, compound B was formed as the major product.
Spectral data for B: HNMR / ppm: 4.75, singlet, 2H; 2.1, quartet, 2H; 1.9 singlet, 3H and 1.1, triplet, 3H. 13CNMR / ppm: 145, 105, 29, 22, 12.
In contrast, when A was heated with KOH in ethanol, compound C, an isomer of B, was formed as the major product.
Identify A, B and C.
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Organic Chemistry
Authors: Francis Carey, Robert Giuliano
9th Edition
0073402745, 9780073402741
