Question
The simple reversible liquid-phase reaction A 2B takes place in a plug flow reactor. The concentration of A at the entrance of the reactor is
The simple reversible liquid-phase reaction A 2B takes place in a plug flow reactor.
The concentration of A at the entrance of the reactor is 0.5 M, and there is also 11 M of an inert solvent. Neglecting the volume change, find the equilibrium yield of the reaction as function of the temperature. Plot or sketch the respective equilibrium composition vs. temperature.
Parameters: fH(A) = -130 kJ/mol fH(B) = -45 kJ/mol fG(A) = -145 kJ/mol fG(B) = -70 kJ/mol (standard state 1 M) cp(A) = 70 J/molK cp(B) = 30 J/molK cp(solvent) = 17 J/molK k = 180*exp(-EA/RT) min-1M-1, where EA = 30 kJ/mol.
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