Question
The slope (d P /d T ) of the solid-liquid phase boundary is much steeper than the liquid-gas phase boundary, and both slopes are positive.
The slope (dP/dT) of the solid-liquid phase boundary is much steeper than the liquid-gas phase boundary, and both slopes are positive. Explain this behaviour
D Supercritical fluid 72.9 atm Liquid Solid Pressure (not to scale) 5.1 atm Gas 1 atm B 31 C -78.5C -56.7 C Temperature (not to scale) Y Pressure, P 0 Mole fraction of B, X6 1
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Elementary Principles of Chemical Processes
Authors: Richard M. Felder, Ronald W. Rousseau
3rd Edition
978-0471687573, 9788126515820, 978-0-471-4152, 0471720631, 047168757X, 8126515821, 978-0471720638
