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The Wilson equation provides the following expression for the excess Gibbs free energy for a binary system: ( Delta G ^ EX ) /
The Wilson equation provides the following expression for the excess Gibbs free energy for a binary system:
Delta GEXRTx lnxLambda x x lnxLambda x
Here x and x are mole fractions, while Lambda and Lambda are binary interaction parameters that characterize the specific binary system their values are independent of xi
Can the Wilson equation describe phase separation? If so under what conditions? Show your work by taking the appropriate derivative of the expression for Delta GMixture. HINT: For phase operation, Gxinstability; Delta GMixture Delta GEX xlnx xlnx
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