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To manufacture chlorine, H C l and O 2 react to form C l 2 and H 2 O . To drive this reaction and

To manufacture chlorine, HCl and O2 react to form Cl2 and H2O. To drive this reaction and
achieve 85% fractional conversion of HCl, sufficient air (21%O2,79%N2) is fed into the plant, at
35% excess oxygen.
a) Use molecular species balance or atomic species balance to calculate the mole fractions (Y)
of all chemical components (i.e.,HCl,O2,N2Cl2,H2O).
Hints: Begin by balancing the chemical reaction:
HCl+
O2
Cl2+
ntot,,out=??nj=nHCl+nO2+nN2+nC2+nH2O
b) Using the extent of reaction method instead, determine the molar output for each species.
You note that an alternative to using air as an O2 source would be to feed pure O2 to the
plant reactor.
c) Speculate on potential costs / savings to justify whether it's worth using pure O2 for the
process.
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