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Water ( 6 0 l b moles ) , benzene ( 2 0 l b moles ) , and toluene ( 2 0 l b

Water (60lb moles), benzene (20lb moles), and toluene (20lb moles) equilibrate as a liquid
mixture at a pressure of 0.9atm. The water (W) and the organics are immiscible, and the
benzene (B) and the toluene (T) form an ideal mixture.
The following ratios of vapor pressures can be assumed constant over the temperature range of
interest:
PBPW=2.11
PTPW=0.813
At the bubble-point temperature and the specified system pressure, the saturation pressure
(atm) of water, Pw, is most nearly:
(A)0.23
(B)0.37
(C)0.62
(D)0.76
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