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( Welty 2 5 . 3 , 6 6 t h edition ) A hemispherical droplet of liquid water, lying on a flat surface, evaporates

(Welty 25.3,66th edition) A hemispherical droplet of liquid water, lying on a flat surface,
evaporates by molecular diffusion through still air surrounding the droplet. The droplet initially
has a radius R. As the liquid water slowly evaporates, the droplet shrinks slowly with time, but
the flux of the water vapor is at a nominal steady state. The temperature of the droplet and the
surrounding still air are kept constant. The air contains water vapor of fixed concentration at
an infinitely long distance from the droplet's surface. After drawing a picture of the physical
process, select a coordinate system that will best describe this diffusion process, list at least five
reasonable assumptions for the mass-transfer aspects of the water-evaporation process, and
simplify the general differential equation for mass transfer in terms of the flux NA. Finally,
specify the simplified differential form of Fick's flux equation for water vapor (species A), and
propose reasonable boundary conditions.
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