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When compound D was treated with HBr in CH2Cl2 with exclusion of light compound E was produced. However, when the reaction was conducted in the

When compound D was treated with HBr in CH2Cl2 with exclusion of light compound E was produced. However, when the reaction was conducted in the presence of peroxides product F was obtained. Write out stepwise mechanisms for these two products and briefly summarize why the different results are obtained.

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HBr,ROOR HBr,CH2Cl2 F D E

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