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Why are ester - type plasticizers so commonly used for PVC and cellulosics? Why are ionomers superior to polyethylene in strength, transparency, and adhesion? What

Why are ester-type plasticizers so commonly used for PVC and cellulosics?
Why are ionomers superior to polyethylene in strength, transparency, and adhesion?
What is the effect of cross-linking on modulus, strength, creep resistance, maximum
use temperature, and solvent resistance?
Why are thermosetting adhesives often the strongest?
Assuming we can calculate total intermolecular attraction & bonding, how useful is
this in explaining effects on properties?
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