At high temperature, Cu 3 Au has a disordered fcc structure with space group Fm3m. On cooling,
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At high temperature, Cu3Au has a disordered fcc structure with space group Fm3m. On cooling, an ordering transition occurs and the low-temperature structure has space group Pm3m with Au at 0 0 0 (Wyckoff site 1a) and Cu at ½ ½ 0 (3c).
(a) Sketch the low- and high-temperature structures.
(b) Is this a translationengleiche or klassengleiche transition?
(C) State the number of domain variants in the low-temperature structure and whether they will be related by twin or antiphase boundaries.
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Related Book For
Solid State Materials Chemistry
ISBN: 9780521873253
1st Edition
Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt
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