(a) For a dilute gas, the pair correlation function (g(r)) may be approximated as [g(r) simeq exp...
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(a) For a dilute gas, the pair correlation function \(g(r)\) may be approximated as
\[g(r) \simeq \exp \{-u(r) / k T\}\]
Show that, under this approximation, the virial equation of state (10.7.11) takes the form
\[\frac{P V}{N k T} \simeq 1-2 \pi n \int_{0}^{\infty} f(r) r^{2} d r\]
where \(f(r)[=\exp \{-u(r) / k T\}-1]\) is the Mayer function, equation (10.1.6).
(b) What form will this result take for a gas of hard spheres? Compare your result with that of Problem 1.4.
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