Write the structures of the initially formed enol tautomers in the reactions of propyne and dicyclohexylethyne with

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Write the structures of the initially formed enol tautomers in the reactions of propyne and dicyclohexylethyne with dicyclohexylborane followed by NaOH and H2O2 (Problems 44, part i, and 45, part i).

(a) D2, Pd – CaCO3, Pb(O2CCH3)2, quinoline;

(b) Na, ND3;

(c) 1 equivalent HI;

(d) 2 equivalents HI;

(e) 1 equivalent Br2;

(f) 1 equivalent ICl;

(g) 2 equivalents ICl;

(h) H2O, HgSO4, H2SO4;

(i) dicyclohexylborane, then NaOH, H2O2.

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Organic Chemistry structure and function

ISBN: 978-1429204941

6th edition

Authors: K. Peter C. Vollhardt, Neil E. Schore

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