CuSO 4 5H 2 O containing 3.5 percent of a soluble impurity is dissolved continuously in sufficient
Question:
CuSO4·5H2O containing 3.5 percent of a soluble impurity is dissolved continuously in sufficient water and recycled mother liquor to make a saturated solution at 80°C. The section is then cooled to 25°C, and crystals of CuSO4·5H2O are thereby obtained These crystals carry 10 percent of their dry weight as adhering mother liquor. The crystals are then dried to zero free water (CuSO4·5H2O). The allowable impurity in product is 0.6 percent. Calculate
(a) The weight of water and of recycled mother liquor required per 100 kg of impure copper sulfate;
(b) The percentage recovery of copper sulfate, assuming that the mother liquor not recycled is discarded. The solubility of CuSO4·5H2O at 80°C is 120 g per 100 g of free H.O and at 25C is 40 g per 100 g of free H2O.
Step by Step Answer:
Unit Operations Of Chemical Engineering
ISBN: 9780072848236
7th Edition
Authors: Warren McCabe, Julian Smith, Peter Harriott