Sulfide ion was determined by indirect titration with EDTA. To a solution containing 25.00 mL of 0.04332

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Sulfide ion was determined by indirect titration with EDTA. To a solution containing 25.00 mL of 0.04332 M Cu(ClO4)2 plus 15 mL of 1M acetate buffer (pH 4.5) were added 25.00 mL of unknown sulfide solution with vigorous stirring. The CuS precipitate was filtered and washed with hot water. Then ammonia was added to the filtrate (which contained excess Cu2+) until the blue color of Cu(NH3)42+ was observed. Titration of the filtrate with 0.03927 M EDTA required 12.11 mL to reach the murexide end point. Calculate the molarity of sulfide in the unknown.
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