The associated Legendre functions Pl|m| (w) are defined by Verify that P00(w) = 1, P01(w) = w,

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The associated Legendre functions Pl|m| (w) are defined by
The associated Legendre functions Pl|m| (w) are defined by
Verify that

Verify that P00(w) = 1, P01(w) = w, P11(w) = (1 - w2)1/2 and find P02(w), P12(w), and P22(w). It can be shown that (Pauling and Wilson, page 129)

The associated Legendre functions Pl|m| (w) are defined by
Verify that

Equations (5.146) and (5.145) give the explicit formula for the normalized theta factor in the angular-momentum eigenfunctions. The normalized eigenfunctions of L2 and Lz (the spherical harmonics) are given by Eqs. (5.146) and (5.99) as

The associated Legendre functions Pl|m| (w) are defined by
Verify that

The phase of the normalization constant of the spherical harmonics is arbitrary (see Section 1.7). Many texts use a different phase convention than in (5.147). Thus Yml differs from text to text by a minus sign.

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Quantum Chemistry

ISBN: 978-0321803450

7th edition

Authors: Ira N. Levine

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