The net potential energy between two adjacent ions, E N , may be represented by the sum
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The net potential energy between two adjacent ions, EN, may be represented by the sum of Equations 2.8 and 2.9; that is,
Calculate the bonding energy E0 in terms of the parameters A, B, and n using the following procedure:
(a). Differentiate EN with respect to r, and then set the resulting expression equal to zero, since the curve of EN versus r is a minimum at E0.
(b). Solve for r in terms of A, B, and n, which yields r0, the equilibrium interionic spacing.
(c). Determine the expression for E0 by substitution of r0 into Equation 2.11.
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Fundamentals of Materials Science and Engineering An Integrated Approach
ISBN: 978-1118061602
4th Edition
Authors: David G. Rethwisch
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