The phosphorus tri-halides (PX3) show the following variations in the bond angle X-P-X: PF3, 100.3o, PCl3, PBr3,
Question:
(a) Assuming that all electron domains are the same size, what value of the angle is predicted by the VSEPR model?
(b) What is the general trend in the X-P-X angle as the halide electro-negativity increases?
(c) Using the VSEPR model, explain the observed trend in X-P-X angle as the electro-negativity of X changes.
(d) Based on your answer to part (c), predict the structure of PBrCl4.
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a PX 3 26 valence e 13 pairs 4 electron domains around P tetrahedral e domain geometry if all bondin...View the full answer
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Related Book For 
Chemistry The Central Science
ISBN: 978-0321696724
12th edition
Authors: Theodore Brown, Eugene LeMay, Bruce Bursten, Catherine Murphy, Patrick Woodward
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